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This is a diagnostic test - we use it to determine where extra mathematical help is needed for the class as a whole and where you get to see specific areas where you may need to work on your mathematical skills. The diagnostic test DOES NOT count in any way towards your first year grade.

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For the following convert between the specified units.

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5 nJ to J;

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5 × 10[[0]] J

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25 µmol dm−3 to mol m−3

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25 × 10[[0]]  mol m−3

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1780 cm−1 to m−1

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     1.780 ×10[[0]] m−1

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Rearrange the following equations for the variable specified:

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When typing your answer:

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Find z where G = -zVF

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$z = $[[0]]

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Find ΔS where ΔG = ΔH−TΔS

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$\\Delta S = $[[0]]

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Normally you would represent this as a single fraction over a common denominator, rather than two separate fractions over the same dehominator.

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Combine the following and rearrange to make the mass m the subject, in terms of only concentration, c, volume, V and molar mass, Mr.

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$n=\\frac{m}{M_r}$ & $n=cV$

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$m = $[[0]]

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The energy in J of a photon on frequency $\\nu$ (greek letter nu) is given by:

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$E=h \\nu$

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The speed of light, c, is related to this frequency and the wavelength, $\\lambda$.

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$c=\\lambda \\nu$

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The energy in electron volts is given by:

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$E_{eV} = \\frac{E}{e}$

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Where $e$ is the charge on an electron.

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Write an expression for the energy of a photon in eV as a function of wavelength.

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$E_{eV}=$[[0]]

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Calculate the following:

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ΔS represents the change in entropy of the system between its final state, Sf and its initial state Si.

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Calculate ΔS when Sf = 3.2 J K1 mol1 and Si = 7.2 J K1 mol1

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Determine, and use, the appropriate number of decimal places for your answer.

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ΔS = [[0]] J K1 mol1

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Determine the pOH of a solution of 0.01 mol dm−3 HCl.

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pOH = [[0]]

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Find the pKa if the pH=7.1 and the amount of dissociation, x = 0.4

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$\\mathrm{pK_{a}}=\\mathrm{pH} - \\log_{10}\\frac{x}{1-x}$

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Determine, and use, the appropriate number of decimal places in your answer.

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$\\mathrm{pK_{a}}$ = [[0]]

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The emf (voltage on a voltmeter) is being calibrated. The relationship is given by:

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$ emf = K + 0.059 ~\\mathrm{pH} $  

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When the pH = 7 exactly the emf = 0.240 V, calculate the pH when the emf = 0.490 V?

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Determine, and use, the appropriate number of decimal places in your answer.

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pH = [[0]]

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Fill in the empty boxes:

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(when entering powers of ten please type in as 1.234e+5 to represent \"$1.234 \\times 10^5$\". NOTE:you must include either a + or - after the e)

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103 / T / K−1108 k / dm3 mol−1 s−1T / ºCk / dm3 mol−1 s−1
3.1722.73[[0]][[1]]
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In an experiment where you vary the temperature, T, and measure the rate constant, k, what would you plot on the x- & y-axes to give the most appropriate linear plot given you are fitting the data to the following equation:

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$k= Ae^{-\\frac{E_a}{RT}}$

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Please check your answer in the preview which will appear, you will need to use brackets around variables if they are subject to a mathematical function.

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(if using exponents in your answer please enter in the form e^(x), if using logarithms please enter in the form ln(x) for natural logs and log(x) for log to the base 10)

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x-axis:    [[0]]

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y-axis:    [[1]]

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When typing your answer:

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The answer will show a preview - please ensure this is as you expect, particularly with fractions, logarithms and multiplied expressions.

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Your use of significant figures will be assessed - ensure you are always using appropriate significant figures relevant to the problem posed.

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Rearrange to give an expression for $V_i$ where:

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$\\Delta S = R \\ln \\frac{V_f}{V_i}$

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$V_i=$[[0]]

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It is not normal to leave answers as fractions; use superscript notation instead.

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Find the order of reaction, n, given that the initial concentration of the reactants [A]0 = 0.1 mol dm−3 and the initial rate is 0.01 mol dm−3 s−1 given as:

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'rate' $=[A]^n$

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n=[[0]]

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Determine the following:

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When typing your answer:

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The answer will show a preview - please ensure this is as you expect, particularly with fractions, logarithms and multiplied expressions.

\n

\n

Your use of significant figures will be assessed - ensure you are always using appropriate significant figures relevant to the problem posed.

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when $E = BJ(J+1)$

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$\\frac{\\textrm{d}E}{\\textrm{d}J}$=[[0]]

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when $V=\\frac{A}{R^{12}}-\\frac{C}{R^6}$

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\n

$\\frac{\\textrm{d}V}{\\textrm{d}R}=$[[0]]

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Determine the following:

\n

\n

When typing your answer:

\n\n

The answer will show a preview - please ensure this is as you expect, particularly with fractions, logarithms and multiplied expressions.

\n

\n

Your use of significant figures will be assessed - ensure you are always using appropriate significant figures relevant to the problem posed.

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$\\int k \\textrm{d}t$

\n

\n

[[0]]

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$\\int \\frac{1}{p}\\textrm{d}p$

\n

\n

[[0]]

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$\\int \\frac{1}{T^2}\\textrm{d}T$

\n

\n

[[0]]

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Determine and rearrange the answer to the simplest expression:

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$-\\int_{V_i}^{V_f}\\frac{nRT}{V}\\textrm{d}V$

\n

\n

[[0]]

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This can be simplified by application of the rule of logs

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You have 5 minutes remaining, the exam will automatically time out when your time is up.

"}}, "feedback": {"showactualmark": false, "showtotalmark": false, "showanswerstate": false, "allowrevealanswer": false, "advicethreshold": 0, "intro": "

Please read these instructions carefully:

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To progress through the test please select the question in the left hand column. Some questions have multiple parts.

\n

Some questions require you to type in algebraic expressions. When typing your answer:

\n\n

The answer will show a preview - please ensure this is as you expect, particularly with fractions, logarithms and multiplied expressions.

\n

\n

Your use of significant figures will be assessed - ensure you are always using appropriate significant figures relevant to the problem posed.

\n

\n

On the final page, after submission, you are given the option to download or print transcript. Please print this to pdf for your own records.

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