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The chemical potential of a substance in a mixture, $\\mathrm{\\mu_x}$, is given by the following equation:

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$\\mathrm{\\mu_x={\\mu_x}^\\circ + RTln(a_x)}$ ,

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where $\\mathrm{{\\mu_x}^\\circ}$ is the standard chemical potential of the substance, in $\\mathrm{J \\space mol^{-1}}$;  $\\mathrm{R=8.314\\space J \\space K^{-1}\\space mol^{-1}}$ is the universal gas constant;  $\\mathrm{T}$ is the temperature of the system, in $\\mathrm{K}$; and $\\mathrm{a_x}$ is the activity (effective concentration) of the substance, which is unitless.

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We are asked to calculate the activity of sulfur trioxide when its chemical potential is $\\mathrm{\\mu_{_{SO_3}}=\\var{sigformat(p,5)}\\space kJ\\space mol^{-1}}$. We convert the chemical potential by multiplying by one thousand, to $\\mathrm{{\\mu_{_{SO_3}}}=\\var{sigformat(pot,5)} \\space J \\space mol^{-1}}$ .

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We are given the standard chemical potential of sulfur trioxide, $\\mathrm{{\\mu_{_{SO_3}}}^\\circ =\\var{gso3} \\space kJ \\space mol^{-1}}$, which we convert by multiplying by one thousand, to $\\mathrm{{\\mu_{_{SO_3}}}^\\circ =\\var{sigformat(realg,4)} \\space J \\space mol^{-1}}$ .

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To calculate the activity value, $\\mathrm{a_{_{SO_3}}}$, we must rearrange our original equation appropriately, then simply substitute our values into the equation and evaluate:

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$\\mathrm{\\mu_{_{SO_3}}={\\mu_{_{SO_3}}}^\\circ + RTln(a_{_{SO_3}})}$

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$\\mathrm{\\Rightarrow\\space\\space\\space ln(a_{_{SO_3}})=\\frac{[\\mu_{_{SO_3}}-{\\mu_{_{SO_3}}}^\\circ]}{RT}}$

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$\\mathrm{\\Rightarrow\\space\\space\\space a_{_{SO_3}}=exp(\\frac{[\\mu_{_{SO_3}}-{\\mu_{_{SO_3}}}^\\circ]}{RT})}$

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$\\mathrm{\\Rightarrow\\space\\space\\space a_{_{SO_3}}=exp(\\frac{[\\var{sigformat(pot,5)}-\\var{sigformat(realg,4)}]}{8.314\\times 298 })=\\var{sigformat(a,3)}}$ .

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The standard chemical potential of sulfur trioxide in a mixture is found to be $\\mathrm{\\var{gso3}\\space kJ\\space mol^{-1}}$ at $\\mathrm{298\\space K}$.

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What must the activity of the sulfur trioxide be when its chemical potential is found to be $\\mathrm{\\var{sigformat(p,5)}\\space kJ\\space mol^{-1}}$?

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[[0]]

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