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Q1   Unit Conversion    [9 marks]

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Consider the visible region of the electromagnetic spectrum:

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In many applications the photon frequency is conveniently represented with units Terahertz (THz).  Recall:   1 THz = 1012 Hz

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In many forms of spectroscopy the photon energy is more conveniently expressed as the photon wavenumber, , in cm-1.  Consider, for example, the abscissa (x-axis) values presented in infrared spectra.

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Useful Information
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Wave equation:          Planck Relation:       where 

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Q1

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(a) (i)       = {299800 * lambda} THz.       Then round answer to 2 significant figures

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(a) (ii)  Conversion factor:       Wavenumber:     

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          Specific answer:      {10000000 / lambda} cm-1.      Then round answer to 2 significant figures

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(b)  Conversion factor:         Answer:  Reciprocal area = {Inv_area} × 1019 × 10-20 = {0.1 * Inv_area} Å-2      Then round answer to 2 decimal places

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SJK

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Q1 (a) (i)

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Calculate the photon frequency, in THz, of {lambda} nm light.  Report your answer to 2 significant figures.

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Q1 (a) (ii)

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Calculate the photon wavenumber, in cm-1, of {lambda} nm light.  Report your answer to 2 significant figures.

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Q1 (b)  Diffraction

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Diffraction is an experimental technique used by chemists to probe the structural properties of solids.  The details of such experiments will be explored in future undergraduate lectures.

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A common quantity that arises from diffraction measurements is a reciprocal area with units m-2.  This quantity is then converted to a value with units Å-2, an important step when extracting information concerning spacings between particles.

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A value of the reciprocal area was determined as {Inv_area} × 1019 m-2.  Convert this quantity to units Å-2.  Report your answer to 2 decimal places.

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